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Beilstein J. Org. Chem. 2016, 12, 198–203, doi:10.3762/bjoc.12.22
Graphical Abstract
Figure 1: a) Asymmetric α-hydroxylation of 2 in the presence of 1a. b) Asymmetric α-amination of 4 explored i...
Scheme 1: Substrate scope of α-amination.
Figure 2: NLE study of α-amination.
Scheme 2: α-Amination of 4a using 9 or 10 as catalyst.